Yes, but only with some affiliates. A lot of our affiliates do not have this service yet. If the product you are interested in has urgent shipping, you will see a text in brown saying "Urgent shipping available" on the product's file's shipping information part, under the unit price. You will keep seeing it on the trolley and on the delivery options at the end of the order. To choose this option, bellow your delivery details, on the pull-down menu "Shipping options", change the option to the most urgent. It will tell you the urgent delivery, delivery period and price. By default, the system applies the standard shipment option to your order. Remember that this shipment option, when it's available, is faster, but it is more expensive.
Another option to check what products have urgent shipping is as follows: choose a type of product like wine, sparkling wine, beer, distillates, etc. and the select the option "Urgent shipment" within the shipment filter (on our example it takes us to http://www.uvinum.co.uk/wines:h:express-shipping). Here you will see all the available products with urgent shipping.